Radical polymerization in disperse systems

acrylamide acrylonitrile adsorbed AIBN amphiphile anionic Appl aqueous phase average number butyl acrylate Candau carboxyl groups Chem coagulation coefficient Colloid Colloid Interface Sci conversion copolymerization decrease desorption diameter diffusion disperse phase dispersion polymerization distribution effect El-Aasser emulsifier emulsifier concentration emulsifier molecules emulsion polymerization formation formed free radicals function graft copolymer hydrophilic increase initiator concentration interaction inverse emulsion inverse microemulsion ionic kinetic latex latex particles latices layer lipophilic Makromol mass mechanism methacrylic acid methyl methacrylate micellar micelles microemulsion mol dm monomer concentration monomer droplets Napper nonionic emulsifier nucleation number of particles number of radicals oil phase oligomeric radicals parameters particle number particle surface peroxodisulfate Phys poly(styrene polymer dispersions polymer particles polymerization of styrene polymerization rate prepared presence primary particles propagation rate constant rate of polymerization ratio seed solubility solution solvent steric stabilizer structure styrene suspension polymerization temperature termination Vanderhoff vinyl acetate viscosity water-soluble