Organic Chemistry of Synthetic High Polymers

acetate acid active addition reaction alkyl aluminum amounts anionic apparently approximately atom carbon catalyst cationic cause Chem chloride combination complex compounds concentration containing conversion copolymer copolymerization crosslinking crystalline cyclic decrease depending determined discussed double bond effect endgroups energy Equation ether ethylene example formation formed free-radical groups high molecular weight higher hydrogen important increase indicate initiation involving kinetic latter linear Makromol mechanism melting merization metal methacrylate methyl mole molecular weight molecules monomer observed obtained occur olefin organic oxide Patent peroxide poly polyesters polymer chain Polymer Sci polymerization reaction prepared presence probably propagation radical rate constants ratio reactivity relative repeating units resonance result ring shown solvent stabilization step step-growth step-growth polymerization structure styrene substitution Table temperature termed termination tion titanium transfer transition values vinyl yields York