Copolymerization: Toward a Systematic Approach
Springer Science & Business Media, 1999 - 228 páginas
Copolymerization is a very widely used industrial process, in fact the dominant process in macromolecular chemistry. With the advent of widespread computing power, this book will be very useful both to academic researchers in copolymerization and to researchers in industry concerned with the synthesis of polymers such as plastics, rubbers, chemical fibers, and paints. A disk with 15 computer programs accompanies the book.
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Acrylamide Acrylic Acid Acrylonitrile Acrylonitrile Acrylonitrile antepenultimate model binary copolymerization butyl acrylate charge transfer complex comonomer feed composition complex-participation model composition curve composition data composition equation confidence region conversion values copolymerization of styrene copolymerization process copolymerization systems Dioxane effect emulsion emulsion copolymerization equation 1.9 estimation of reactivity experimental data experimental errors experimental points Figure fit the experimental fumaronitrile high conversions intersection method intersection points kinetic model KT method lateral azeotropes low conversions maleic anhydride Maleimide Mayo–Lewis Mayo—Lewis equation methacrylate Methyl methacrylate Methacrylic acid Methacrylonitrile Methyl acrylate Methyl methacrylate Methyl molar mole fraction monomer nonlinear number of experimental obtained overall copolymer composition pair of reactivity parameters penultimate model polymer PROCOP program Pyridine reaction reactivity ratios determined reactivity ratios estimated Recalculated solvent Styrene Styrene Styrene styrene—maleic anhydride styrene—methyl Succinimide Table terminal model ternary azeotrope tion TM method Vinyl acetate Vinyl chloride Vinylidene chloride