Principles of PolymerizationWiley, 2004 M02 9 - 848 páginas The new edition of a classic text and reference The large chains of molecules known as polymers are currently used in everything from "wash and wear" clothing to rubber tires to protective enamels and paints. Yet the practical applications of polymers are only increasing; innovations in polymer chemistry constantly bring both improved and entirely new uses for polymers onto the technological playing field. Principles of Polymerization, Fourth Edition presents the classic text on polymer synthesis, fully updated to reflect today's state of the art. New and expanded coverage in the Fourth Edition includes: * Metallocene and post-metallocene polymerization catalysts * Living polymerizations (radical, cationic, anionic) * Dendrimer, hyperbranched, brush, and other polymer architectures and assemblies * Graft and block copolymers * High-temperature polymers * Inorganic and organometallic polymers * Conducting polymers * Ring-opening polymer ization * In vivo and in vitro polymerization Appropriate for both novice and advanced students as well as professionals, this comprehensive yet accessible resource enables the reader to achieve an advanced, up-to-date understanding of polymer synthesis. Different methods of polymerization, reaction parameters for synthesis, molecular weight, branching and crosslinking, and the chemical and physical structure of polymers all receive ample coverage. A thorough discussion at the elementary level prefaces each topic, with a more advanced treatment following. Yet the language throughout remains straightforward and geared towards the student. Extensively updated, Principles of Polymerization, Fourth Edition provides an excellent textbook for today's students of polymer chemistry, chemical engineering, and materials science, as well as a current reference for the researcher or other practitioner working in these areas. |
Contenido
STEP POLYMERIZATION | 40 |
28c2 Utility | 92 |
28g | 101 |
Derechos de autor | |
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Términos y frases comunes
acrylate acrylonitrile active alkenes anionic behavior block copolymers C. G. Overberger carbocation carbon carboxyl catalyst cationic polymerization CH₂ chain end chain polymerizations chain transfer Chap Chem chloride conversion copolymer composition copolymerization counterion crosslinking crystalline cyclic ethers decreases degree of polymerization depending double bond effect end groups ester ethylene functional groups H. F. Mark increases initiator involves ion pairs ionic isoselective isotactic kinetic lactam living polymerization M₁ M₂ Macromolecules Makromol merization metallocene methyl methacrylate molecular weight molecules monomer monomer reactivity ratios monomer units N. M. Bikales nucleophilic obtained occurs oxide Penczek polar poly polymer chain polymer molecular weight Polymer Science polymerization rate propagating centers propagating chain propagating radicals propagating species r₁ r₂ radical polymerization rate constants reactants reaction system ring Ring-Opening Polymerization solvent step polymerization stereoselectivity steric structure styrene substituents syndiotactic synthesis temperature termination tion values vinyl acetate Wiley-Interscience yield Ziegler-Natta