Copolymerization: Toward a Systematic ApproachSpringer Science & Business Media, 2012 M12 6 - 228 páginas Copolymerization is a very widely used industrial process, in fact the dominant process in macromolecular chemistry. With the advent of widespread computing power, this book will be very useful both to academic researchers in copolymerization and to researchers in industry concerned with the synthesis of polymers such as plastics, rubbers, chemical fibers, and paints. A disk with 15 computer programs accompanies the book. |
Contenido
| 1 | |
Estimation of Reactivity Ratios | 19 |
25 | 57 |
Ternary Copolymerization | 101 |
Going Beyond the Limits of the Terminal Model | 131 |
Not Homopolymerize | 157 |
Homogeneous and Heterogeneous Copolymerization | 181 |
Running a Copolymerization Process | 214 |
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Términos y frases comunes
Acrylamide Acrylonitrile antepenultimate model Appl azeotrope binary copolymerization butyl calculated charge transfer complex Chem comonomer feed composition complex-participation model composition curve composition data composition equation confidence region conversion values copolymerization of styrene copolymerization process copolymerization systems discrimination emulsion copolymerization equation 1.9 experimental data experimental errors experimental points Figure fit the experimental fumaronitrile G. E. Ham high conversions intersection points kinetic model KT method lateral azeotropes M₁ M₂ Macromolecules Makromol maleic anhydride Mayo-Lewis equation methacrylate Methyl methacrylate Methacrylonitrile Methyl acrylate Methyl methacrylate Methyl methacrylate Methyl molar mole fraction monomer nonlinear number of experimental obtained optimal overall copolymer composition pair of reactivity parameters penultimate model Polym PROCOP program propagation step Q-e scheme r₁ r₁₂ r₂ reaction reactivity ratios reactivity ratios determined reactivity ratios estimated Recalculated solvent Styrene styrene-maleic anhydride Table terminal model ternary azeotrope ternary copolymerization tion TM method Vinyl acetate Vinyl chloride Vinylidene chloride