Lecture Notes on Solution ChemistryWorld Scientific, 1995 - 242 páginas This book emphasises those features in solution chemistry which are difficult to measure, but essential for the understanding of both the qualitative and the quantitative aspects. Attention is paid to the mutual influences between solute and solvent, even at extremely small concentrations of the former. The described extension of the molecular concept leads to a broad view ? not by a change in paradigm ? but by finding the rules for the organizations both at the molecular and the supermolecular level of liquid and solid solutions. |
Contenido
Development and Present State | 1 |
The Phase Boundary of Liquid Water | 10 |
Atoms and Molecules | 11 |
Chemical Bonding | 18 |
Interactions between Molecules | 25 |
The Liquid State | 39 |
Anomalous Physical Properties of Liquid Water | 53 |
Bond Length Considerations | 66 |
102 | 133 |
Solvation in NonAqueous Solvents | 145 |
Ionization and Association in NonAqueous Solutions | 157 |
Qualitative Aspects of the Molecular Concept | 169 |
System Organization of Liquid Water | 185 |
Changes in Organization of Liquid Water | 195 |
Water within the Human Body | 205 |
Organization in NonAqueous Solutions | 215 |
Some Trivia about Water | 69 |
Water at Interfaces in Biological Systems | 85 |
Hydrophobic Solutes in Water | 97 |
Hydrophilic Solutes in Water | 109 |
Water and Alcohols | 117 |
Characterization of NonAqueous Solvents | 129 |
117 | 217 |
Intramolecular System Organizations | 225 |
| 232 | |
Epilogue | 233 |
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